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Registration Number

0223U001185, 0122U001961 , R & D reports

Title

Chemical design of multifunctional coordination compounds and bistable supramolecular materials

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Head

Frytskyi Ihor O., Доктор хімічних наук

Registration Date

25-01-2023

Organization

Taras Shevchenko National University of Kyiv

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The object of research: the processes of obtaining new functionalized ligand systems and coordination compounds of transition metals with specified or tunable optical, magnetic and catalytic properties, control of the functional activity of which is achieved through programming of supramolecular interactions. The purpose of the work: application of the principles of molecular design to obtain metal-containing complexes with given optical, thermochromic, magnetic and catalytic properties, followed by correlations between the structure, supramolecular structure and physicochemical properties. Research methods: magnetochemical measurements, X-ray structural analysis, X-ray diffractometry, 57Fe Mössbauer spectroscopy, IR spectroscopy, Raman spectroscopy, elemental analysis, calorimetry, optical microscopy. New tridentate ligands based on N-heterocyclic compounds were synthesized to obtain complexes with iron(II), which are capable of exhibiting a spin transition between high-spin and low-spin states with significant hysteresis at room temperature. New iron-containing complexes with a spin transition based on cyanoborohydride and pyrazine were obtained. Composite films with a spin transition characterized by bistability were obtained and investigated.  

Product Description

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Kucheriv Olesya I.
Plutenko Maksym О.
Seredyuk Maksym L.
Tsapyuk Galyna G.

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2023-01-25