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Information × Registration Number 0120U105253, ( 0221U104180  ) R & D request Title New functional materials for carbon capture and utilization Head Domasevych Kostiantyn V., Доктор хімічних наук Registration Date 02-12-2020 Organization Taras Shevchenko National University of Kyiv popup.description1 To elaborate principles of structure design, innovative methodologies and strategies for supramolecular synthesis involving oxide, fluoride and (oxo)fluorometalate systems and to develop novel materials for applications toward advanced green technologies of carbon dioxide capture and utilization through the use of hybrid ultramicroporous organic-inorganic frameworks and water-resistant ionic metal pyrazolates that 1) maintain a microporous structure with useable pore size for carbon dioxide sorption applications; 2) are stable within a broad temperature range and are chemically robust; 3) are capable of the selective uptake of carbon dioxide within the pores of the structure and/or of the insertion of the substrate with the formation of labile chemical bonds; 4) can reversibly adsorb significant amounts of carbon dioxide; 5) are suited for regeneration and recycling; and 6) combine the above outcomes to produce novel families of functional materials, which rationally address the technological issues of performance at low partial pressures, selectivity at high humidity, thermal and hydrolytic stability, chemical accessibility and meet the cost-effective criteria for practical usage as phisio- and chemisorbents of carbon dioxide for the direct air capture (DAC) and air quality control technologies and as catalysts for chemical utilization of carbon dioxide. popup.nrat_date 2024-12-10 Close