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Information × Registration Number 0200U004297, 0197U018223 , R & D reports Title New finctional monomr and inittioators on the asis of b-dicarboonyl compounds and porphyrinss popup.stage_title Head Voloshanovskyj I.S., Registration Date 16-11-2000 Organization Odessa State University popup.description2 7-unsturated b-diketones, containing in their structure CH3-3,CF3-3,C6H5-funchional groups and differing from cachother b the struchure of hydrocarbonic chain and methacoylacetone are synthesized/ On thtir basis 21 metal cjmplexes of unsaturated b-diketones with Cu(11),Ni(11),Co(11) are synthesized.Their prysical and chemical characteristics are studied, their infra-red spectra are studied and geometric conformation of complexes is determined. Radical poiymerization of atyrene and methylmethacrylte initiated by the synthesizod chemlated is studied. Velocites and energies of activation of polymeization, powers of reaction by monomer and molecular weight distribution of samples of polymers are determined. Conclsions are made about the mechanism with styrene and methylmetacrylate is studied. Kinetic parameters of process, cjmposition, and molecular weight distribution of copolymers are studied. Luminescent characteristixs of copolymers ofcjpolymers with europian(111) are studies. Conchasion anout the pro cess of cjmplecation with polymer lygands and the possibility of using copolymers as organic luminophors are made Product Description popup.authors popup.nrat_date 2020-04-03 Close