Search academic texts

Information × Registration Number 0200U007075, 0197U019588 , R & D reports Title Study of relyativistic effets in the redox-properties of noble metals. popup.stage_title Head Yatsymyrs'kyj Kostyantyn Borysovych, Registration Date 27-12-2000 Organization Institute of Physical Chemistry L.V.Pisarzhevsky NAS Ukraine popup.description2 The systematic study of Pd(II), Pt(II), Ru(II) and Ni(II) complexes with thia- containing ligands is carried out. The synthesized new complexes of Pd(II), and Pt(II), immobilized on a surface of silicon dioxide reveal an unusual structure and properties, their stability and the spectral properties were investigated . New complexes of Pd(II), Ru(II) and Ni(II) with a number of thiaimine and thiaoximato ligands which differ by unusual structural propertieshave been investigated . Properties of these compositions were examined by X-ray crystal analysis, methods of electrochemistry and magnetochemistry. The dependence of redox-behaviour of thiacomplexes on the composition of coordination sphere and charge of a complex particle is considered. It is shown, that the stabilization of oxidation state of platinum + 4 is explained by display of relyativistic effects. Product Description popup.authors popup.nrat_date 2020-04-03 Close