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Information × Registration Number 0201U003260, 0198U002173 , R & D reports Title The influence of heterometalic carboxylates composition and nuclearity on the dibenzyl ether and cyclohexene conjugate liquid-phase oxidation selectivity. popup.stage_title Head Kamalov Gerbert Leonovych, Registration Date 12-02-2001 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 Is established, that in conditions of dibenzyl ether liquid-phase oxidation in the presence of heterometalic - oxotrimetalhexapivalates of chromium(III) the hydroperoxide formation and its transformation to benzaldehyde (BA) take place on the same catalytic center. The synergism of a catalytic action of water and investigated metal complexes is detected. Is established, that BA is an effective component of conjugate liquid-phase oxidation of cyclohexene at the presence of polynuclear of cobalt, chromium, iron, nickel and vanadyl pivalates with metal core M M O. Is revealed, that main products of this process are cyclohexene hydriperoxide, cyclohexene-3-ol, cyclohexene -3-on and cuclohexene oxide. Product Description popup.authors popup.nrat_date 2020-04-02 Close