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Information × Registration Number 0201U003710, 0198U003027 , R & D reports Title Kinetics and mechanisms of electrophilic reactions of hydrocarbons with a peroxynitrite, permanganil-cation and suported complexes Pd(II) popup.stage_title Head Rudakov Yelisej Sergijovych, Registration Date 06-04-2001 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 It has been established that alkylbensenes oxidation by MnO3+ cation occurs by the mechanism of electrophilic aromatic substitution through a transition state being spontaneous to a sigma-complex and a complex with a charge transfer. It has been established that a OH-radical or a ОН..NO2 radical pair is an active particle in the reaction with HOONO. A new variant of kinetic distributive method of measuring constants of reaction rates of gaseous substrates with reaction centres on the surface has been developed. Kinetics and mechanism of the ethylene oxidation by Pd(II) complexes put on SiO2 have been studied. It has been shown that toluene in the presence of Pd(II) complexes and Mo,V-heteroacids-of 12th range put on SiO2 is transformed into methyldiphenyl-methanes (ditolyls haven't been found). Тhere are in agreement with the mechanism of single - electron transfer. Product Description popup.authors popup.nrat_date 2020-04-02 Close