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Information × Registration Number 0204U000330, 0102U001307 , R & D reports Title Research of electrochemical active particles and multielectronic electrochemical processes making mechanism in ionic melts with wolframates and molibdates. popup.stage_title Head Solovyov Veniamin Vasylievich, Registration Date 30-01-2004 Organization Polava National Technical University named in the honour of Yuri Kondratyuk popup.description2 By holding the quantum chemical calculation the method SCF MO LCAO with the help of the software packages GAMESS and HyperСhem7 on a basis of the previously designed microscopic theory of the between-particles of interactions and the processes of the electrorestoring in ionic melts the fundamental principle asid-basically catalysis is advances, which is proves the priority influence of the cation-аniоs of interactions on the mechanism of the formation of the electrochemically active particles (EAP) in a Wolframat- and Molybdenum-containing melts and defines a directedness of the processes electrorestoring of the anions and the control facility of these processes. The characteristic types EАP, their power and charge performances are established. Is proved, that owing to the cation-аniоs of interaction there is the reduction of magnitudes of the аctivation barriers at the electrorestoring for a cation-аniоs. The offered technique quantum chemical of an estimation stages of the multielectronic processes is perfected earlier.The priority of the one-phasic six-electronic restoration above of the on-phasic for the outwardly-sphere cations forms EАP is established. The results can find application in the heterogeneous catalysis, the high-temperature electrochemistry, in the field of the galvanotechnics, аt deriving of the high-dispersible powders and the sheetings from ionic melts, and other. Product Description popup.authors popup.nrat_date 2020-04-02 Close