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Information × Registration Number 0204U005075, 0101U001529 , R & D reports Title Cationotropic isomerization in unsymmetrical acyloines range. popup.stage_title Head Ivonin Sergey Pavlovich, Registration Date 04-03-2004 Organization Dniepropetrovsk national university popup.description2 Reseash object - nonsymmetrical acyloines having heteryl and aryl substitutents. Aim of work - reseaching of nonsymmetrical acyloines chemical properties, such as their - -isomerization. Reseach method - synthesis of nonsymmetrical acyloines, determination of factors influencing on the - -isomerization proceeding. Aryl and heteryl glyoxales addition to -riched heterocycles let obtain with high yields -acyloines. Obtaining -acyloines isomerize at -acyloines at base conditions. The nonsymmetrical acyloines structures influence and reaction conditions influence at - -isomerization proceeding was found. For N,N-dimethylhydrazone of furfurole derivatives of isomeric acyloines structure influence at furane substitutents reactivity was found. Obtaining rules have important mean as at theoretical organic chemistry as at applied tasks of organic synthesis. Product Description popup.authors popup.nrat_date 2020-04-02 Close