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Information × Registration Number 0205U004559, 0102U003257 , R & D reports Title A study of heterophase heterogeneous electrochemical processes involving complex formation at the electrode. popup.stage_title Head Kublanovsky Valery Semonovich, Доктор хімічних наук Registration Date 13-04-2005 Organization National Academy of Scienіses of Ukraine, Council of Productive Forces Studies of Ukraine popup.description2 Report on research work: 100 pages, 23 figures, 12 tables, _____ additions, 77 references. Object under investigation: heterophase heterogeneous electrochemical processes involving formation electrochemically active complexes at the electrode. Purpose of the work: investigation of complex self-consistent electrochemical and electrocatalytic processes, involving electrochemically active complexes, at the interface between two or three phases, which occur in electrochemical cells, function electroplating equipment, sensors, full cells, and electrocatalytic nanostructures. Methods of investigation: synthesis of electrocatalytic nanostructures with carbon matrix based on 3d-metal complexes, chemical analysis, pH potentiometry, mathematical simulation method, voltammetry, rotating disk electrode method, electrolysis. In the work, electrocatalytic nanostructures with carbon matrix based on 3d-metal complexes have been synthesized and investigated in real gas-diffusion electrodes in oxygen reduction reaction; the effect of electrochemically active complexes on the kinetics of electrochemical process stages has been established for the deposition of silver, palladium and copper-tin alloy from a phosphate-borate-carbonate, a glycinate and a citrate electrolyte as an example; results of studying the anode-corrosion behavior of silver and gold as a function of electrolyte composition are presented. Conditions of the receiving of the report: on a contractual basis. V.I. Vernadskii Institute of General and Inorganic Chemistry, Ukrainian National Academy of Sciences, prospekt Palladina 32-34, 03680 Kyiv -142. Product Description popup.authors popup.nrat_date 2020-04-02 Close