Search academic texts

Information × Registration Number 0207U000917, 0104U000317 , R & D reports Title Influence of a electrode surface and electric field on reactionary ability EAP in ionic melts popup.stage_title Head Solovyov Veniamin Vasylievich, Registration Date 15-02-2007 Organization Polava National Technical University named in the honour of Yuri Kondratyuk popup.description2 By the conducting of ab initio calculations influencing of the main factors of influencing is learned: acid-base properties of environment, external electric field and adsorption properties of the surface of electrode both on the mechanism of the EAP forming in fusions melts, and on reactionary ability of these EAP in the processes of renewal. It is proved, that the acid-base mechanism of the EAP forming into tungsten and molibdates melts is taken to priority formation of the cationazed anions. It is shown, that the surface of electrode and electric field practically do not affect the character of the cation-anion interaction, however their restoration ability is multiplied by the decline of height of activating barriers of renewal. The alternative of stage of processes of transfer of charge at the design of multielectronic reactions of the EAP renewal is explored. Priority of simultaneous transfer of charge is found out on EAP before successive caused outer-spherical catonization of "isolated" anion,which initiates realization of different coordinates of electrochemical reaction at simultaneous and successive processes of transfer of charge. Product Description popup.authors popup.nrat_date 2020-04-02 Close