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Information × Registration Number 0207U005095, 0104U002019 , R & D reports Title Kinetics and mechanisms of the reactions of hydrocarbons with peroxynitric acid and oxocomplexes vanadium(V) popup.stage_title Head Elisey S. Rudakov, Registration Date 01-03-2007 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 The new data on kinetics, influence of a structure of a substrate, conditions of a reaction and presence of gas and hydrocarbon phases on the oxidation mechanisms of alkanes and alkenes by peroxynitrous acid have been obtained. It is shown, that an active particle in reactions of hydrocarbons in a gas phase and in a water solution are the OH-radicals formed at homolytic dissociation of peroxynitrous acid. Kinetics, substrate selectivity and activation parameters of reactions of benzene and alkylbenzenes with the metavanadic acid in sulfuric acid solution have been studied. It is shown, that an active particle is vanadium dioxоcations; the reaction is determined by the arene ionization potential. The first example of three-parameter compensation relationships is established. Product Description popup.authors popup.nrat_date 2020-04-02 Close