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Information × Registration Number 0207U006203, 0102U000119 , R & D reports Title Modelling of catalytic systems on the base of mono and polynuclear chromium complexes in reactions of hydrogen peroxide wuth alcogol and olefins popup.stage_title Head Kamalov G.L., Registration Date 28-03-2007 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 The means of obtaining of the aliphatic and cycloaliphatic crown ethers complexes with halogenodiperoxochromates are modified. The intermediates of alcohols oxidation to carbonyl compounds by these complexes are corresponding esters of peroxo- and hydroperoxochromates. The liquid-phase oxidation of acenaphthene and cyclohexene by air in the presence of 3d metals homonuclear pivalates are disclosed. The products of dibenzyl ether oxidation by H2O2 in the presence of pivalates are hydroperoxide (HP), BAld and BAc. Complexes exhibit noticeable selectivity for HP (58%) and BAld (48%) are disclosed Product Description popup.authors popup.nrat_date 2020-04-02 Close