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Information × Registration Number 0209U001482, 0106U000253 , R & D reports Title Scientific knowledge for synthesis and reactivity of N, S-heterocycles to obtain compounds with predicted properties. popup.stage_title Head Markov Victor Ivanovich, Registration Date 05-02-2009 Organization State higher educational entity "Ukrainian State University of Chemical Technology" popup.description2 Objects of research: N-, S-containing heterocyclic compounds – substitution N-sulphonylaziridins, derivatives of condensation of the cyclohexanone with urea and thiourea; compounds on a basis of N- and S-amidoalkylation, amides of hetaren-2-thiocarboxylic acids and their functional derivatives; quinone compounds; electroanalitical characteristics of the film and solid contact ion selective electrodes, reversible to organic cations; catalytic reactions on synthetic metallic silicates. Methods of investigation: Precise organic synthesis, thin-layer chromatography, spectral methods of analysis, ionometric and amperometric titration. Results of investigation: were synthesized – hydrazides on a basis substituted N-sulphonylaziridins, derivatives of Quinazolinone and Quinazolinthione; derivatives of oxazole, thiazole, oxadiazole; thiadiazole, imidazo[2,1-b][1,3,4]-thiadiazole; N3-arylamidrazones of hetaren-2-carboxylic acids, substituted 1,5-tetrazole, substituted 3,4,5-triazole, new coordination compoundsof Cu(II), Cu(III); conditions of course of the reaction of arenal-azines 1,4-benzoquinonediimine with chloride-anion, n-toluolsulphinate-anion and n-toluidine; was studied influences of obtaining methods of Cu-Zn-Al hydrotalcits on their catalytic properties in organic synthesis, in direct synthesis indole from ethylenglicole and aniline influence of the nature of the carrier on activity of Cu-containing contacts is investigated; ion selective electrodes, reversible to determined organic cations were elaborated, dependence of composition of membrane of ion selective electrode on nature of organic cations, heteropolyaniones, EAC, membrane solvent-plasticizer. Fields of the usage: Organic and petrochemical engeeniring, production of pharmaceuticals, means of plant protection. Product Description popup.authors popup.nrat_date 2020-04-02 Close