Search academic texts

Information × Registration Number 0209U005352, 0105U002636 , R & D reports Title Sensibilization of dioxygen (О2), hydrogen (Н2О2), peroxyde and organic hydroperoxides (ROOH) by mono- and polynuclear complexes of 3 d-metals with polydentate (including macroheterocyclic) ligands. Modeling of catalytic systems of selective liquid-phase oxidation of organic substrates. popup.stage_title Head Kamalov Gerbert Leonovich, Registration Date 11-02-2009 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 Studied connection of catalytic properties (activity, selectivity) of mono- and polinuclear 3d metals carboxylates with their composition and structure (nature of metal, structure of ligand, nuclearity) in liquid-phase oxidation of organic substrates by air, hydrogen peroxide, and in hydrogen peroxide decomposition. Obtained new podands and crown ethers complexes with chromium (VI) compounds, their catalytic properties are studied in the interphase, homogeneous and heterogeneous oxidation processes. Synthesized podands series on the basis of imidazole and tiazole derivatives - perspective ligands for the synthesis of 3-d metals complexes with the specified composition and structure. Product Description popup.authors popup.nrat_date 2020-04-02 Close