Search academic texts

Information × Registration Number 0209U008622, 0109U006991 , R & D reports Title Spectral studies of transformation products with the participation of nanocarbenes and benzoin condensation reaction popup.stage_title Head Korotkikh Nikolai Ivanovich, Доктор хімічних наук Registration Date 19-11-2009 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 The goal of the work is spectral studies of catalytic transformation products with the participation of nanocarbenes and benzoin condensation reaction. Spectral properties of new palladium nanocarbene complexes on the basis of mononuclear 1,2,4-triazol-5-ylidenes, pyrazolin-5-ylidenes, 3,3'-bridged bis-1,2,4-triazol-5-ylidenes, chelated palladium heteroaromatic carbene complexes of the 1,2,4-triazole series, products of polyquaternization of diimidazolyl- alkanes by dichloroalkanes, a precursor of planar imidazo[4,5-d]imidazol- 2,5-diylidene, the corresponding bisimidazolium salt, were studied by NMR spectrosopy method. The data obtaned have significance for spectral identification of carbenes, carbene complexes of metals and their precursors. The application area is analysis of stable carbenes and carbene complexes. Product Description popup.authors Єня Василь Іванович Зарайський Анатолій Павлович Кисельов Артем Вікторович Кнішевицький Артур Володимирович Короткіх Микола Іванович Марічев Констянтин Олександрович popup.nrat_date 2020-04-02 Close