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Information × Registration Number 0210U001865, 0108U002389 , R & D reports Title "Novel chalcohalides of transition metals and complex compounds on their basis (synthesis, struture, physico-chemical properties" popup.stage_title Head Volkov Sergiy Vasyliovych, Registration Date 23-04-2010 Organization V.I.Vernadskii Institute of General and Inorganic Chemistry NASU popup.description2 Depending on synthesis temperature and "heating-colling" conditions in nonaqueous media (Sе2Cl2, S2Cl2, solution of S in Sе2Cl2, solution of Sе in S2Cl2, solution of S inS2Cl2) novel rhodium, ruthenium, rhenium, osmium and iridium chalcochlorides have been obtained: : Rh2Se8Cl5, Rh3SCl9 2,5H2O, Rh2S8Cl5O2 4H2O, Rh2Se7Cl5, RhS9Se6Cl4, Rh4Se18Cl10, Rh4Se16Cl10, Rh4Se14Cl10, Ru2Se9Cl6, Ru7S3Cl77, Ru10S4Cl30, Ru3S9Se4Cl10O3, Ru2S6Se8Cl4O, Re3S5Se2Cl7, Re3S6.5Se0.5Cl7, Os3S7SeCl8, OsSe2Br12, OsTe2Br12, IrSe5Cl4, IrS4Se4Cl4, Ir2S4Se3Cl8 H2O, IrS3Cl5 2H2O, Ir2S3Cl7 5H2O, IrS4Cl3 3H2O, Ir2S5Cl6 4H2O. Novel metal chalcochlorides: Rh2Se6Cl5, Rh3Se3Cl, Rh3SCl9, Rh2S7Cl3, Rh4S9Cl2, Rh4Se12Cl8, Rh4Se5Cl5, Rh4Se5Cl3, Rh2S16Se10Cl6, Rh4S5Se4, Rh4S5Se3, Rh3Se5Cl, Rh10SeCl, Re3S3SeCl3, Re3S2Se, Re3S3.6Se0.4Cl3, Re3S2.7Se0.3, Os3S6SeCl7, Os3S3Se, Os3S2Se have been obtained by the thermal destruction in vacuo of some of the above compounds at different temperatures. Their structure and properties have been studied. The catalytic properties of rhodium chalcochlorides in processes of nitro group hydration into amine group of organic compounds and preparation of alcohols from synthesis gas have been investigated. Product Description popup.authors Александрова Ніна Георгієвна Машкова Емілія Михайлівна Харькова Людмила Борисівна Янко Олег Георгієвич popup.nrat_date 2020-04-02 Close