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Information × Registration Number 0210U004200, 0106U001195 , R & D reports Title Designing the "green" microheterogeneous systems for decomposition of ecotoxicants popup.stage_title Head Anatolii F.Popov, Доктор хімічних наук Registration Date 22-03-2010 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 Supernucleophilic systems on the basis of functional detergents (FD) involving imidazolium/pyridinium core and alfa-nucleophilic moiety (oximate group) have been proposed for decomposition of organo-phosphorus compounds (OPC). Interrelation between basicity and nucleophilicity of oximate group in FD was first established, with the prospects for designing the purpose-directed detergents. Reactivity of comprehensive oxidation-nucleophilic systems in water, in the presence of detergents, and in microemulsions has been studied. Cetyltrimethylammonium dibromobromate was found to be a unique reactant which forms micelles and oxidation-nucleophilic couple BrO-/HOBr, and the most efficient compound in decomposition of OPC, phenols, etc. It has been shown that the "green" systems hydrogen-peroxide/activator provide fast and irreversible decomposition of a variety of ecotoxicants. Product Description popup.authors Бєлоусова І.О. Бураков М.І Вахітова Л.М. Гайдаш Т.С. Зубарева Т.М. Капітанов І.В. Карпічєв Є.А. Кострикин М.Л. Мітченко О.С. Михайлов В.О. Панченко Б.В. Прокоп'єва Т.М. Разумова Н.Г. Садовський Ю.С. Скрипка Г.В. Соломойченко Т.М. Таран Н.А. Тицький Г.Д. Туровська М.К. Шумейко О.Є. popup.nrat_date 2020-04-02 Close