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Information × Registration Number 0210U006866, 0110U005344 , R & D reports Title Elaboration of detoxication methods for halogenaromatic compounds, pesticides, pharmaceutical preparations and wastes of their production popup.stage_title Head Popov Anatolii Fedorovich, Доктор хімічних наук Registration Date 16-12-2010 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 The syntheses of polymer carbene complexes of palladium (0, ІІ) and nickel (0, ІІ), monomer carbene complexes of nickel and palladium (0, ІІ) were carried out on the basis of conjugated bridged 3,3'-phenylen-bis-1-tert-butyl-4-phenyl- 1,2,4-triazol-5-ylidenes, 1-tert-butyl-3,4-diaryl-1,2,4-triazol-5-ylidenes and 1,4-diphenyl-1,2,4-triazolium-3-phenylimide, the synthesis of p-xilylendiimidazolium and heterylendiimidazolium salts was also performed for polymer carbene complexes on their basis. It was shown that monohalogen substituted arenes undergo dehalogenation in milder conditions than polyhalogen derivatives. The catalysts obtained have higher level of catalytic activity in the dehalogenation reaction of halogenarenes than the known analogues. Product Description popup.authors Єня Василь Іванович Глиняна Наталія Валеріївна Кисельов Артем Вікторович Короткіх Микола Іванович Кочканян Роберт Ованесович Пехтерева Тетяна Михайлівна Сабєров Вагіз Шамільович Смоляр Микола Миколайович popup.nrat_date 2020-04-02 Close