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Information × Registration Number 0211U001096, 0106U001144 , R & D reports Title New molecular receptors and supramoleculars of catenanes and rotaxanes types: synthesis, structure and properties. popup.stage_title Head Lukyanenko N.G, Registration Date 18-01-2011 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 Research object - azacyclophanes, cyclophanes, crownophanes and [2] catenanes on their basis, derivativates of diphenylglycoluril, containing the fragments of benzocrown ethers. and their complexes with organic molecules and ions of metals. A purpose of work is synthesis of cyclophanes, azacyclophanes, fluorenonocrownophanes, fluorenocrownophanes; molecular clips on the basis of diphenylglycoluril and benzocrown ethers; study of structure of the synthesized compounds and their interaction with cations of metals and organic molecules; synthesis of psevdorotaxanes and catenanes on the basis of fluorenonocrownophanes. Research methods - synthetic, IR, UV, NMR spectroscopy, mass spectrometry, X-ray. The methods of synthesis are developed and fluorenonoazacrownophanes is received and their ability effectively enough to extract cations of alkaline metals and ammonium from a water phase in chloroformic solution is shown. Bisfluorenonophanes, in which two fragments of fluorenone are bound by rigid xilylenes bridges is synthesized. The methods of synthesis of new class of molecular clips on the basis of diphenylglycoluril and benzocrown ethers are developed, the structure of which is proved spectral methods and X-ray analysis. Product Description popup.authors Богащенко Т.Ю Кікоть Л.С Кириченко Т.І. Кулигіна К.Ю Лобач О.В. Лук'яненко М.Г Ляпунов О.Ю. Пастушок В.М Яковенко І.С. popup.nrat_date 2020-04-02 Close