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Information × Registration Number 0211U001205, 0109U006369 , R & D reports Title Nanocatalysis of organic reactions: development of carbene and metalcomplex nanocatalysts and their use in the reactions of С-С and С-Heteroatom bond formation popup.stage_title Head Shvaika Oles Pavlovych, Registration Date 25-01-2011 Organization Donetsk National University popup.description2 The synthesis of nanokarben nickel and palladium chelate type complexes was elaborated. Their catalytic properties in the dehalogenation reaction of arenes are studied. The paths of interaction of 1,4-biphenyl-1,2,4-triazolium-3-phenilimid with transition metal salts were investigated. It was shown that copper salts(I) formed mono-and biscarben nanocomplexes. The new in the complex compound chemistry imidometallocarben rearrangement was develuped. The resulting complexes are suitable for catalysis of reduction reactions of multiple hetherobonds. The work was performed at the level of laboratory research. The results obtained are recommended for use in preparative organic synthesis for the preparation of stable carbenes and their complexes of transition metals (palladium, copper, nickel, and also calcium) and precursors of nanokarben catalysts. Product Description popup.authors Доценко Ірина Микитівна Короткіх Микола Іванович Сабєров Вагіз Шамілевич popup.nrat_date 2020-04-02 Close