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Information × Registration Number 0211U007065, 0109U001090 , R & D reports Title The influence of composition and structure of 3d metal complexes with N-, O- and S-containing hetero- and macrocyclic polydentate ligands on peroxo-bonds (O-O) formation and decomposition in catalytic liquid-phase oxidation of organic substrates popup.stage_title Head Kamalov Gerbert Leonovich, Registration Date 22-03-2011 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 The kinetics of hydrogen peroxide decomposition and dibenzyl ether's liquid-phase oxidation was investigated in the presence more than 30 carboxylates and carboxylate-pyrazole complexes of cobalt and copper (with nuclearity of 1-7). Catalytic properties of these complexes were compared. The conditions of desulfurization products' which obtained by the alkylation of 6-methyl-2-thiouracil with aliphatic, cycloaliphatic and aromatic alfa-bromketones were studied. The synthesis methods of the 2-betta-oxoalkylpyrimidines which coordinated 3d metals were developed. Product Description popup.authors Іванов Ю.Е. Грищук Л.В. Коцеруба В.А. Краєвська Н.С Літвінова Л.В. Левченко О.О., Степанов Д.Є Чіхічін Д.Г Яволовський А.О popup.nrat_date 2020-04-02 Close