Search academic texts

Information × Registration Number 0211U009103, 0106U006627 , R & D reports Title Direct synthesis and biological properties of transition metal heteropolynuclear complexes. popup.stage_title Head Kokozay V.N., Доктор хімічних наук Registration Date 24-06-2011 Organization Taras Shevchenko Kiev university popup.description2 The behavior of the anionic complexes in direct synthesis of heterometallic complexes based on Fe or Cr was studied and shown that this complex is the source of metaloligand or building blocks, or a source of metal for other building blocks. The methods of direct synthesis of heterometallic complexes, based on the interaction of metal (or metal oxide) with non-aqueous solution of anionic complexes in the presence of complexing reagent, was developed. According to developed procedure heterometallic complexes were synthesized and their structure was set by X-ray analysis. The magnetic properties of the synthesized complexes was studied and found that the compounds Cu/Fe and Cd/Cr exhibit weak antiferromagnetic properties. In complex Mn/Cr ferromagnetic interaction is realized between the central atoms of chromium (III) and manganese (II). Product Description popup.authors Бєлінська І.В. Бувайло О.А. Гарманчук Л.В. Дубова О.О. Карпезо Н.О. Кокозей В.М. Островська Г.В. Петрусенко С.Р. Позур В.К. Поліщук В.П. Рибальченко В.К. Рибальченко Т.В. Синельник Т.Б. Сківка Л.М. Фурзікова Т.М. Харіна А.В. Шкорбатов Ю.Г. Яворська Н.В. popup.nrat_date 2020-04-02 Close