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Registration Number

0211U009457, 0110U003424 , R & D reports

Title

Design of nanoreactors for tuning reactivity by covalent and non-covalent amphiphiles functionalization

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Head

Popov Anatolii Fedorovich, Доктор хімічних наук

Registration Date

20-12-2011

Organization

The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry

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Objects of investigation: organized nanosized systems based on dimeric and functionalized surfactants. Methods of synthesis of novel monomeric functionalized, dimeric, and functionalized dimeric surfactants are elaborated. Physico-chemical properties of novel dimeric surfactants and their binary mixtures with cationic surfactant, and also reactivities of alpha effect nucleophiles are investigated using UV, IR, NMR spectroscopy, pH-metry, optical microscopy, and DSC techniques. "Structure-reactivity" regularities in nanosized surfactant-based systems are set. Design principles for environmentally friendly micellar nanoreactor with tunable reactivity are elaborated. Results are important for development of theory of structure and properties of organized molecular and supramolecular systems, in practical work they may be used in nanotechnologies and for decontamination of environmentally unfriendly compounds.

Product Description

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Анікєєв О.В.
Капітанов І.В.
Карпічев Є.А.
Кострікін М.Л.
Михайлов В.О.
Прокоп'єва Т.М.
Разумова Н.Г.

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2020-04-02