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Information × Registration Number 0211U009520, 0107U000061 , R & D reports Title The development of the scientific approaches to the formation of the chiral calixarenes as building blocks of the supramolecular catalysts and functional nanostructures. popup.stage_title Head Kalchenko Vitaliy Ivanovich, Доктор хімічних наук Registration Date 26-12-2011 Organization Institute of Organic Chemistry National Academy of Sciences of the Ukraine popup.description2 The aim of the research - design and synthesis of new types of chiral calixarenes available for the creation of the functional nanostructural supramolecular materials, catalysts for asymmetrical synthesis and materials for enantioseparation of organic molecules' optical antipodes. The methods of regio- or stereoselective calixarene functionalization were elaborated, in particular the approach to the synthesis of the inherently chiral calix[4]arenes with asymmetrically macrocyclic skeleton substitution was worked out and the effective method of the obtaining of optically pure inherently chiral calixarene carboxylic acids and its amides was proposed. The optically pure derivatives of chiral calixarenes were obtained and their physical-chemical properties, spatial structure and absolutely configuration were investigated by means of X-ray analysis, NMR and IR-spectroscopy. Product Description popup.authors Єсипенко Олександр Адольфович Атамась Людмила Іванівна Бойко В'ячеслав Іванович Вишневський Сергій Григорович Довгоп'ята Лідія Соловеївна Драпайло Андрій Богданович Мірошниченко Станіслав Іванович Матвєєв Юрій Іванович Пироженко Володимир Валентинович Поволоцький Марко Йосипович Родік Роман Васильович Роженко Олександр Борисович Рубан Олександр Володимирович Тернова Дарія Сергіївна Цимбал Іван Федорович Черенок Сергій Олексійович Чернега Олександр Миколайович Ющенко Олександр Анатолійович popup.nrat_date 2020-04-02 Close