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Information × Registration Number 0211U013223, 0107U000064 , R & D reports Title New principles of creation of reagents which introduce of fluoroalkylcontaining groups into organic compounds to get of a useful complex of biological, physical and chemical properties. popup.stage_title Head Yagupolskii Yurij Lvovich, Доктор хімічних наук Registration Date 11-01-2012 Organization Institute of Organic Chemistry National Academy of Sciences of the Ukraine popup.description2 The goal of investigation was a purposeful elaboration of synthetic methods to develop new fluorocontaining reagents for introduction of polyfluoroalkyl groups into organic molecules. These investigations open wide outlook for the preparation of biological active compounds, drugs, chemical sources of electrical energy, etc. In contras with others known methods of perfluoroalkylftion we first synthesized a new reagents for electrophylic perfluoroalkylation - diaryltrifluoromethyl-sulfonium salts. A new types of fluoroalkylation agents on the base fluorocontaining metal organic compounds were elaborated. Principle new method of synthesis of previously unknown thiacyanine dyes with perfluoromethyne chain was created. The method of preparation of the first Fisher's carbene complexes with perfluoroalkyl- and trifluorovihyl groups was developed. Electrophylic perfluoroalkylation with a new trifluoromethylated reagents was first carried out. A new types of fluoroalkylating metal organic compounds which are perspective for the study of various aromatic and heterocyclic compounds were developed. Scientific results of this investigation can be used in the fields of organic, elementoorganic and fluoroorganic chemistry. Product Description popup.authors Бойко Володимир Миколайович Кирій Наталія Владленівна Кремльов Михайло Михайлович Малєтіна Ірина Ісааківна Матюшечева Галина Іванівна Мушта Олексій Іванович Орлова Раїса Кузьмівна Павленко Наталія Віталіївна Петко Кирило Ігоревич Писаренко Марія Михайлівна Соколенко Тарас Михайлович Філатов Андрій Анатолійович Чернега Оксана Іванівна Шеляженко Світлана Володимирівна popup.nrat_date 2020-04-02 Close