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Information × Registration Number 0211U013430, 0110U000377 , R & D reports Title Solvation and polarization effects of nano dimension molecules in radical reactions' catalysis popup.stage_title Head Polunkin E., Registration Date 29-12-2011 Organization Institute of Bioorganic Chemistry and Petrochemistry of National Academy of Sciences of Ukraine popup.description2 It has been Established nonmonotonic change rates constant breakage of chains initiated oxidation of benzyl alcohol for peroxyl radicals of chlorinated Fullerens in depending on their degree of chlorination. It has been shown that C60Cl12 is most effective inhibitor in series C60Cl6, C60Cl12 C60Cl28. The influence of the phenomenon of local ordering of molecules of liquid environment around nanoscale cluster compounds on catalytic conversion of free radicals with molecular oxygen oxidation of liquids. The calculation of parameters of domains (number of molecules in the domain and the size of a single domain) for nonpolar and polar environments isooctane environment ethanol in the presence of these fluids halogenated fullerene C60F48. Discovered the phenomenon of catalysis chain breakage nitrogen oxidation of benzyl alcohol ekzoedral fullerenes. Product Description popup.authors Є.В. Шелудько В.С. Пилявський Р.С. Жила Т.М. Каменєва popup.nrat_date 2020-04-02 Close