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Information × Registration Number 0212U002358, 0111U009722 , R & D reports Title Directed formation of porous coordination polymers with high-spin metal centers popup.stage_title Head Pavlishchuk Vitaliy Valentinovich, Registration Date 10-02-2012 Organization Institute of Physical Chemistry L.V.Pisarzhevsky NAS Ukraine popup.description2 Structure, sorption and magnetic properties of a series of new porous coordination polymers, built on the basis of high-spin "building blocks" - polynuclear heterometallic complexes of Cu(II) and lanthanide ions (Pr, Nd, Sm, Eu, Gd) of composition {[(LnCu5(GlyHA)5(H2O)5]2[Cu(C2O4)2][Cu(C2O4)2(H2O)]2}n and {[(GdCu5(GlyHA)5(H2O)7Cr(C2O4)3]}n (where GlyHA is the anion of glycinehydroxamic acid) were studied. Sorption and magnetic properties of polynuclear complexes [Cu5(ahpha)4(m-C8H4O4)(H2O)] и [Cu5(ahpha)4(p-C8H4O4)(H2O)2]2 (where ahpha is dianion of N-hydroxy-3-(hydroxyamino)-3-iminopropanamide, and C8H4O4 is corresponding isomer of phthalate-ion), {Fe2MO(Piv)6}8{L1}12 (L1 = 2,6-bis-(4-pyridyl)-4-(4-dimethylaminophenyl)pyridine) and Fe2MO(Piv)6{M'(L2)2}2 (M = Ni, M' = Co, or M = Co, M' = Ni; L2 = Schiff base from isoniazide and 2-pyridinecarbaldehyde) were studied. Magnetic properties of complexes [SmCu5(GlyHa)5]2(SO4)3 and [NdCu5(GlyHa)5]2(SO4)3 were studied. Product Description popup.authors Гавриленко К.С. Дорофєєва В.М. Колотілов С.В. Литвиненко А.С. Павліщук В.В. Полунін Р.А. popup.nrat_date 2020-04-02 Close