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Information × Registration Number 0212U004135, 0109U000125 , R & D reports Title Physical and chemical processes at nanostructured systems popup.stage_title Head Vargalyuk Viktor Fedorovich, Доктор хімічних наук Registration Date 30-01-2012 Organization Dniepropetrovsk national university popup.description2 The object of investigation is electrochemical precipitating of d4-d10 metals and stages of its electrodepositions. The aim of investigation is determination of the nature of dominant factors which are determined features of transfer of electrochemically atomized metal to nanostructured form. Methods of investigation are potentiostatic and galvanostatic; quantum chemical modeling of metal complexes (with program GAMESS); potentiostate PI-50-1 with programmer PR-8, oscillographes C9-8 and C-19, computer. Theoretical and practical results: The mechanism of zinc nucleus galvanostatic formation on isotropic carbon electrode has been suggested and grounded. Structure of electroactive biligand chromium complexes has been determined. Quantum chemical modeling of copper nucleation initial stages and zinc electroreduction in presence of surface-active substances has been carried out. Energy state of nickel aquacomplexes and nickel water-ammonia and water-cysteine complexes has been correlated. Ability of copper and zinc binuclear complexes with amino-siccine acid has been determined. Properties of protection film on zinc and alloys electroplates has been investigated. Novelty - new original methods of investigation of electrode process kinetics and mathematical models. Field of application are electrochemical and corrosion laboratories in scientific institutions, establishments of engineering and instrument-making. Product Description popup.authors Іванко Вікторія Степанівна Орленко Ольга Сергіївна Петренко Ліна Володимирівна Середюк Володимир Олександрович popup.nrat_date 2020-04-02 Close