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Information × Registration Number 0212U004314, 0107U000407 , R & D reports Title Development of scientific basis for a selective one-step process catalysts produce hydrogen and synthesis of low molecular weight hydrocarbons and oksyhenativ popup.stage_title Head Strizhak Petro Yevhenovuch, Доктор хімічних наук Registration Date 03-02-2012 Organization Institute of Physical Chemistry L.V.Pisarzhevsky NAS Ukraine popup.description2 The main purpose of - developing a scientific basis for selective heterogeneous catalysts for one-step processes of obtaining and purification of hydrogen for use in fuel cells and synthesis of organic compounds, in particular, cyclohexanone, ethyl tert-butyl ether, formaldehyde. In order to develop efficient catalysts for the process of obtaining hydrogen by low-temperature reforming of ethanol detected activity caused Fe/ZrO2 catalyst during steam reforming of ethanol. To obtain efficient materials for hydrogen storage conducted synthesis of carbon nanotubes on transition metals and defined their sorption properties. Shown that the adsorption of nitrogen occurs mainly on the outer surface of the nanotubes and not inside their internal cavities. In order to develop effective new generation of catalysts for removing carbon monoxide from hydrogen for use in hydrogen fuel cell developed a catalyst for selective oxidation of CO in rich hydrogen mixtures. A typical Fischer-Tropsch synthesis is a large number of by-products, output of which is characterized by low selectivity. As a result of research developed selective catalysts for propylene,?-Olefins (C4-C6) and a broad fraction of hydrocarbons (C2-C8) from synthesis gas. During the oxidation of methane to methanol and formaldehyde to dramatically increase the speed and selectivity of the process shows that the catalyst is able to generate methyl radicals in the interaction of methane with him, which accelerates the process chain, but it will hardly affect the yield of methanol and formaldehyde. Promising substitute for methyl tert-butyl ether, used as high-octane component of gasoline is ethyl-tert-butyl ether in the synthesis of which can use ethanol. The process of heterogeneous catalytic synthesis of ethyl tert-butyl ether. It is shown that fosfatovane coal is very active and selective catalyst in heterogeneous catalytic synthesis of ethyl tert-butyl ether. Experimental study of industrially important catalytic dehydrogenation process tsykloheksanolu, which is one of the key technologies in the synthesis of caprolactam in the presence of copper-containing catalysts show that the modification of catalysts CuOx-WO3 promotes exit cyclohexanone in the dehydrogenation tsykloheksanolu without loss of selectivity for the target product. Product Description popup.authors іденко Ольга Захарівна Бичко Ігор Б. Власенко Ніна Василівна Гриценко Валентина Іванівна Гуральський Андрій Володимирович Гурнік Тетяна Миколаївна Дейнега Ігор Васильович Долгіх Лідія Юріївна Калішин Євген Юріевич Кальчук Наталія Сергіївна Космамбетова Гульнара Радіївна Кочкін Юрій Миколайович Лемеш Наталія Вікторівна Луньов Микола Кирилович Пятницький Юрій Ігорович Серебрій Томіла Григорівна Стара Лариса Олександрівна Столярчук Ірина Леонідівна Тарковська Вера Миколаївна Трипольський Андрій Іккійович Хаврусь Вячеслав Олександрович Якубович Михайло Миколайович popup.nrat_date 2020-04-02 Close