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Information × Registration Number 0212U009132, 0112U004234 , R & D reports Title The new functional hybrid materials based on metal-organic framework compounds and semiconductor nanoparticles popup.stage_title Head Lampeka Yaroslaw Dmytrovich, Доктор хімічних наук Registration Date 11-01-2013 Organization Institute of Physical Chemistry L.V.Pisarzhevsky NAS Ukraine popup.description2 For hybrid materials based on metal-organic frameworks (MOF) and semiconductor precursors were synthesized a series of complexes of copper (II), zinc (II), cadmium (II) and nickel (II) with various sulfur-containing ligands and temperature ranges studied their transformation sulfides. As porous matrix were used several different types of MOF chemical nature, coordination polymers based on macrocyclic nickel ion and porous matrix based on polyoxometalates. Stoichiometric parameters determined sorption processes precursors with different types of MOF and show that the treatment of the above composites based ammoniate copper (II) sodium sulfide in aqueous solutions leads to the formation of materials containing nanoscale (7-10 nm) particles CuS, which is evident TEM and X-ray diffraction analysis. Influence of reaction conditions on the yield of layered MoS2 during ultrasonic exfoliation massive molybdenum disulfide. A preliminary study of luminescent properties of layered molybdenum disulfide Product Description popup.authors Барна Андрій Володимирович Наумчук В.Г. Цимбал Людмила Володимирівна popup.nrat_date 2020-04-02 Close