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Information × Registration Number 0212U009133, 0111U007234 , R & D reports Title Development of physicochemical principles to create new highly porous metal-organic framework materials for hydrogen storage popup.stage_title Head Lampeka Yaroslaw Dmytrovich, Доктор хімічних наук Registration Date 11-01-2013 Organization L.V.Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine popup.description2 Synthesized porous MOF based macrocyclic complexes of nickel (II) and zinc (II) and large trigonal anions benzenetriyl-tribenzoate and meta-and para-substituted triazinbenzoatis Studies of sorption properties obtained by the MOF in relation to nitrogen and hydrogen showed that the maximum sorption capacity among the investigated compounds (specific surface area of 220 m2 / g, sorption capacity for hydrogen of 0.42% by weight at 78 K and 1 atm) typical ionic compound formed zinc complex. Based on the study of sorption properties of porous coordination polymers Fe2MO ((CH3) 3CCO2) 6 (L), where M2 + = Co, Ni, L = tris-(4-pyridyl) pyridine (L1) or tris-(4-pyridyl) triazyn (L2), consisting of crystals of different average size (from 1 to 20 microns) shows that the increase in the average size of crystals and improving crystallinity of samples leads to an increase in sorption capacity for hydrogen from 0.7 to 0.9% (78 K, 1 atm). Product Description popup.authors Барна Андрій Володимирович. Гавриш Сергій Павлович Дорофеєва Валентина Миколаївна Колотілов Сергій Володим ирович Лампека Ярослав Дмитрович Полунін Руслан Анатолійович Цимбал Людмила Володимирівна popup.nrat_date 2020-04-02 Close