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Information × Registration Number 0213U001278, 0110U001241 , R & D reports Title Investigations of transformation of fats and oils raw material to surface-active substances and fuels popup.stage_title Head Melnik Anatoliy, Registration Date 07-02-2013 Organization The Kharkov state polytechnical university popup.description2 The purpose is the research of transformation reaction and development of scientific basics of transformation technology of rape and sunflower-seed oils in to oxygen- and nitrogen-containing cyclic surfactants and can be used in different industry branches. The subject is the kinetics and scientific basics of amidation of rape and sunflower-seed oils by amines and development composition on their base with dispersing, inhibitory, foaming, washing, detergent and other properties. The object is the scientific basics of oxygen- and nitrogen-containing cyclic substances obtaining by amidation of rape and sunflower-seed oils. The research methods are chemical, physical (IR spectroscopy, method of gas-liquid chromatography, thin-layer chromatography), physical-chemical. Theoretical and practical results are the ways of oxygen- and nitrogen-containing cyclic substancesobtainingfrom renewable fat and oil raw materials of our country have been presented, new directions of obtaining and utilization of oxygen- and nitrogen-containing cyclic substances in food and technical fields have been shown. The reaction kinetics of amidation by aminoethylethanolamine with different molar ratio, temperatures in relation of timehave been studied The constants of reaction speed have been founded, the reaction order has beendetermined, the thermodynamic parameters have been estimated. Mathematic models of triacylglycerolamidation reaction have been created, the final products by extraction method from reaction composition have been extracted, and surface active and adsorption properties have been estimated. The final products can be used for obtaining corrosion inhibitor composition for mineralized agent have been determine. Thescientificnovelty is based on the fact that due to the establishing of kinetic laws and thermodynamic specialties of chemical transformations concern direct amidation of oil - fat raw materials it is possible to produce the oxygen - nitrogen containing cyclic substances by new competitive technologies that let create new renewable raw material base in our country to produce a range of the surfactants. The technical conditions of adsorption-active composition for Oil and Gas branch on the basis of investigation resultshave been developed and prepared. Product Description popup.authors Ільїнська Ольга Ігорівна Гетманцев Олександр Михайлович Жуган Оскар Анатольович Крамарев Сергій Олегович Малік Сергій Григорович Матвєєва Тетяна Вікторівна Мельник Анатолій Павлович Папченко Вікторія Юріївна popup.nrat_date 2020-04-02 Close