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Information × Registration Number 0213U003295, 0112U003478 , R & D reports Title Metal-organic frameworks and polynuclear complexes: chemical design, structure-adsorption and magneto-luminescent properties popup.stage_title Head Pavlishchuk Vitaliy Valentinovich, Registration Date 24-01-2013 Organization Institute of Physical Chemistry L.V.Pisarzhevsky NAS Ukraine popup.description2 Methods for new compounds synthesis were developed, namely, a series of new homo- and heterometallic complexes of lanthanides (Tp2Tb)2(Ox), (Tp2Tb)2(diacac), (Tp2Tb)2(pPh(acac))2, (Tp2Tb)2(mPh(acac))2, (TpPyTb)2(pma), (TpPyEu)2(pma) (where Tp = tris-pyrazolylborates of different structure, Ox = oxalate, diacac = bis-acetylacetone, pPh(acac) = 1,4-bis-(pentane-2,4-dione-3-yl)phenylene, mPh(acac) = 1,3-bis-(pentane-2,4-dione-3-yl)phenylene, pma = 1,2,4,5-tetrakis-carboxybensene), coordination polymers with metal core Zn2Eu of composition [(Mepy2py)Zn2Eu(hbzo)6(NO3)]n, [(Mepy2py)Zn2Eu(bzo)6(NO3)]n, [(4-ptz)Zn2Eu(bzo)6(NO3)]n, [(4-ptz)Zn2Eu(hbzo)6(NO3)]n, [(4-py3py)Zn2Eu(bzo)6(NO3)]n, [(4-py3py)Zn2Eu(hbzo)6(NO3)]n, {[Zn2Eu(bzo)6(NO3)]3(3-ptz)2}n, {[Zn2Eu(hbzo)6(NO3)]3(3-ptz)2}n (where Mepy2py = 4-4-(4-N,N-dimethylaminophenyl)-bis-2,6-(4-pyridyl)pyridine, 4-ptz = tris-(4-pyridyl)triazine, 4-py3py = tris-2,4,6-(4-pyridyl)pyridine, 3-ptz = tris-(3-pyridyl)triazine, bzo = 3,5-di(tert-butyl)bensoate, hbzo = 3,5-di(tert-butyl)-4-hydroxybensoate), binuclear copper(II) complexes Cu2(Piv)4(HOpy2py)2, Cu2(Piv)4(Mepy2py)2, Cu2(Piv)4(Etpy2py)2 (where HOpy2py = 4-(4-hydroxy-3,5-di-tert-butylphenyl)-2,6-bis-(4-pyridyl)pyridine, Etpy2py = 4-(4-N,N-diethylaminophenyl)-2,6-bis-(4-pyridyl)pyridine, Piv- = pivalate), coordination polymer [Cu2(Piv)4(Mepy2py)]n, supramolecular compounds based on pentanuclear complexes [Cu5(ahpha)4(DMF)2](C4H5O4)2·2DMF, [Cu5(ahpha)4(C4H5O4)2] (ahpha2- = dianion of N-hydroxy-3-(hydroxyamino)-3-iminopropanamide, C4H5O42- = monoanion of maleate) and porous coordination polymer of iron(III) [Fe2(H2O)2(btc)4/3]Cl2·3DMF. The structures of the majority of synthesized compounds were determined by X-ray, electronic spectra of complexes were studied. Complexes of lanthanides, which possessed discrete structures, were studied by mass-spectrometry. It was shown that synthesized coordination polymers and supramolecular compounds had porous crystal lattices. Product Description popup.authors Василенко І.В. Гавриленко К.С. Дорофеєва В.М. Колотілов С.В. Міхальова О.А. Павліщук В.В. Полунін Р.А. Сотнік С.О. popup.nrat_date 2020-04-02 Close