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Information × Registration Number 0214U006357, 0112U001243 , R & D reports Title Syntheses, spectra and structure investigation and investigation of reaction ability of N-phenylacetyl-(N-phenoxyacetyl-, N-benzilidenacetyl)-1,4-benzoquinoneimines and their analogs. popup.stage_title Head Avdeenko Anatoly Petrovich, Кандидат хімічних наук Registration Date 11-03-2014 Organization Donbass State Engineering Academy popup.description2 Object of research are new N-substituted 1,4-benzoquinoneimines - N-phenyl(phenoxy, benziliden)acetyl-1,4-benzoquinonemonoimines. An subject of research is the investigation of NMR 1H and 13C spectra, X-ray to study the electron effects in molecules of synthesized compounds and particularly to study the influence of para-substituent in aryl fragment on quinoid ring of N-phenyl(phenoxy, benziliden)acetyl-1,4-benzoquinonemonoimines. The methods of investigation are NMR 1H and 13C spectroscopy, X-ray, quantum-chemical calculations. For the first time the electron effects in molecules of N-phenyl(phenoxy, benziliden)acetyl-1,4-benzoquinonemonoimines have been studied on the base of X-ray data and NMR 1H, 13C spectra. Novelty of work are the electron effects in molecules of N-phenyl(phenoxy, benziliden)acetyl-1,4-benzoquinonemonoimines, establishment of mechanism of Z,E-isomerization of these quinoneimines. Results of work considerably expand the theoretical knowledge about structure of N-substituted 1,4-benzoquinoneimines to predict there reaction ability. Product Description popup.authors Авдєєнко Анатолій Петрович Апухтіна Надія Василівна Васильєва Вікторія Михайлівна Гончарова Світлана Анатоліївна Коновалова Світлана Олексіївна Михайличенко Оксана Миколаївна Поліщук Мірослав Вікторович Санталова Ганна Олександрівна Холмовой Юрій Петрович Юсіна Ганна Леонідівна popup.nrat_date 2020-04-02 Close