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Information × Registration Number 0215U001804, 0113U005214 , R & D reports Title French-Ukrainian Network on Molecular Chemistry popup.stage_title Head Karpichev Yevgen Adolfovych, Registration Date 20-05-2015 Organization LM.Litvinenko Institute of Physical Organic and Coal Chemistry popup.description2 Objects of research: surfactants containing boronic acid or oxime functional group, their non-micellized analogs, environmentally friendly organized molecular systems. Methods: NMR, UV and MS, elemental analysis, conductometry, GC. During the project, acid-base equilibria of boronylpyridinium salts in aqueous solutions and in the presence of hydrogen peroxide in a wide pH range were investigated; oxidation of organic sulfides in the presence peroxoboronic acid of was studied on the example diethylsulfide studied. Stability of the oxidative-nucleophilic reactive ion systems based on bis-dibrombromates of dimeris surfactants was studied; products of oximolysis of organophosphorus ecotoxicants and reaction products of the pyridine boronic acids with pentaerythritol derivatives were defined. Scientific merit: the results have scientific significance for the development of the theory of the structure and properties of organized systems. Scientific novelty: approaches to create the efficient oxidation systems based on peroxoboronic acids and the synthesis of polyesters of pyridine boronic acids were developed. Practical significance: obtained rganized systems can find their use for cleavage ecotoxic substrates of different nature and for development of promising synthetic nanomaterials. Product Description popup.authors Аніщенко В.М Капітанов І.В. Лобачов В.Л. Прокоп'єва Т.М. Разумова Н.Г. Чернишова В.В. popup.nrat_date 2020-04-02 Close