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Information × Registration Number 0215U003018, 0112U002294 , R & D reports Title Heterophase synthesis (CVD, template) of new ligands and coordination compounds of Ge, Mo, Gd, Yb - functional materials precursors. popup.stage_title Head Trunova, Registration Date 15-01-2015 Organization National Academy of Scienіses of Ukraine, Council of Productive Forces Studies of Ukraine popup.description2 Synthesis methods of novel mixed-ligand and heterometalic coordination compounds of 3d- and 4f-metals, Ge(IV), Mo(VI) with phosphorus- and sulphur-containing complexones, ?-diketones, carboxylic acid are developed. Their physicochemical, structure, electroluminescent and biochemical properties are studied. Nano-materials based on coordination compounds synthesized - germanium nano- and submicron tubes, lanthanum, copper, manganese complex-oxide coatings, cobalt metallic and oxide structures on carbon nanotubes - are obtained. Morphological features of the growth of the nano-objects obtained by CVD technology and spray-pyrolysis are studied. Metalopolymers based on all unsaturated ?-diketones metalocomplexes synthesized are obtained for the first time. Nano-sized films (~10 - 30 nm thick) based on lanthanides metalopolymers are obtained on silicon lining and planar sandwich-type heterostructures ITO/PEDOT:PSS/[Ln(mphpd)3]n/PVC/Al showing electroluminescence at 21 - 22 V are developed. The metalopolymers obtained can be used as emitting layers in organic electroluminescent devices. Applied results obtained may be used for the synthesis of mono-, mixed-ligand and heterometallic complexes with specified composition with different metals and ligands. These complexes may be used to produce stimulants and drugs, feeding additives and CVD precursors. The fields of application of results obtained are agriculture, medicine, opto- and microelectronics, engineering industry and powder metallurgy. Product Description popup.authors Cлюсарчук Л.І. Іваха Н.Б. Бережницька О.С. Герасимчук А.І. Гудима А.О. Железнова Л.І. Изюмцева Г.А. Міщенко А.М. Макотрик Т.А. Мельник О.В. Осадча О.В. Роговцов О.О. Федоров Я. В. Шовкова А.В. popup.nrat_date 2020-04-02 Close