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Information × Registration Number 0215U004933, 0115U005001 , R & D reports Title French-Ukrainian Network on Molecular Chemistry. Stage 3. "Joint with foreign partners research of organized molecular systems based on dimeric surfactants with functionalized spacer/head group" popup.stage_title Head Karpichev Yevgen Adolfovych, Registration Date 22-12-2015 Organization Institute of Organic Chemistry National Academy of Sciences of the Ukraine popup.description2 Objects of the study - dimeric surfactants with different types of functional groups and environmentally friendly organized molecular systems on their basis. The purpose of research - development of methods for the synthesis of surfactants, their physico-chemical and colloid properties. Methods of research - organic synthesis, NMR, UV spectroscopy, tensiometry, conductivity, dynamic light scattering. Dimeric surfactant with variable (a) alkyl chain length, (b) length and hydrophobicity of the spacer and (c) structure of head group were synthesized and investigated; colloid and the acid-base properties of the mixed micelles of cationic monomeric surfactant were studied. Micellar catalytic systems based on the example of acyl transfer reactions involving hydroxide ion and nanocontainers for binding hydrophobic dyes and analogs of biologically active substances were studied The basic principles of efficient and environmentally benign nanoreactors with tunable reactivity and nanocontainers with controlled solubilization capacity were designed . The novelty of the research: an approach to the creation of micro-heterogeneous systems with controlled properties was developed. The results are important for development of the theory of the structure and properties of nanoscale organized systems. Practical significance: cleavage of ecotoxic substrates; creating nanocontainers for polycyclic aromatic compounds. Product Description popup.authors Капітанов Ілля Володимирович Сабєров Вагіз Шамільович Сердюк Ганна Олександрівна Шумейко Олександр Євгенович popup.nrat_date 2020-04-02 Close