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Information × Registration Number 0215U008504, 0110U004995 , R & D reports Title Electronic and spatial structure of the new compounds with peculiar functional properties. Complex investigation with modern physical-chemical methods. popup.stage_title Head Povolotskiy Mark Iosifovich, Registration Date 28-12-2015 Organization Institute of Organic Chemistry National Academy of Sciences of the Ukraine popup.description2 The main aim of the current comprehensive project includes an implementation of modern physico-chemical methods (NMR spectroscopy, X-ray diffraction, highly effective liquid chromatography) and theoretical approaches for studying peculiarities of electronic, molecular and crystal structure of the large series of new chemical compounds. The objects studied are new organic and organoelement compounds, which are prospective for molecular design, crystal engineering of the functional materials, and chemical catalysis. It has been found that in the solid state viologene analogues possess luminescence, which depends not only on the molecular structure of these species, but also on their molecular organization in crystal, presenting pi-stacking between components, solvatation by solvent molecules and hydrogen bonding in crystal. Several reaction mechanisms have been elucidated with a participation of carbenes, including fluor- and phosphorus-containing, N-phosphanylated, acyclic and heterocyclic ones. By NMR spectroscopy and quantum chemistry and single-crystal X-ray diffraction methods structure and conformational properties have been investigated for the electrophilic and nucleophilic, cyclochiral and internally chiral calixarenes and structurally similar species and their adducts with organic, organoelement and biologically important guest molecules. The investigation carried out within this project meet the current international level and do not have analogs in Ukraine. Product Description popup.authors Власенко Юрій Геннадійович Кальченко Ольга Іванівна Кирильчук Андрій Анатолійович Кузнецова Наталія Йосипівна Пироженко Володимир Валентинович Роженко Олександр Борисович Романіка Тетяна Олексіївна Русанов Едуард Борисович Саава Лейла Луківна Смертенко Олена Аронівна Фалківська Вікторія Володимирівна Чернега Олександр Миколайович Шафранова Валентина Савватіївна popup.nrat_date 2020-04-02 Close