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Information × Registration Number 0216U008124, 0116U007292 , R & D reports Title Study of the photoinduced generation of reactive nitroxyl radicls – intermediates of free radical oxidation by femtosecond laser spectroscopy popup.stage_title Head Kachalova Nataliya Mikhailovna, Registration Date 23-09-2016 Organization LM.Litvinenko Institute of Physical Organic and Coal Chemistry popup.description2 Objects of research - iminoxyl radicals and new approaches of radicals generation by laser impulses. The aimof the project is develop a new approach to the study of photoinduced generation of unstable radicals of diverse structure (N-oxyimides, N-oxybenztriazoles and N-oxyamides). The search of the best approach for rapid photochemical generation of radicals within the millisecond time frame is currently very topical. Research methods - ultraviolet spectroscopy, pulse photolysis. The first phase of the project is devoted to the synthesis of two precursors for generation of N-oxyl radicals: N - tryphenylmethoxyphthalimide and oxalic acid ester of 1-hydroxybenzotriazole. UV properties were determined for a number of different nitroxyl radicals, generated by the interaction between the corresponding N-hydroxyphthalimides and chemical oxidants. Product Description popup.authors В.В. Хоменко В.С.Войцехович К.В.Новікова М.О. Компанець О.В. Раєнко popup.nrat_date 2020-04-02 Close