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Information × Registration Number 0216U008126, 0116U007291 , R & D reports Title The catalytic effect of metal complexes and polynuclear clusters on the homogeneous oxidation of organic compounds popup.stage_title Head Kompanets Mikhail, Registration Date 23-09-2016 Organization LM.Litvinenko Institute of Physical Organic and Coal Chemistry popup.description2 The aim of the project - the investigation of new systems for the positive and negative catalysis - aerobic oxidation initiation (or inhibition). Nitroxyl radicals or their complexes were used as catalyst. Interaction of radical precursor - N-hydroxyimides, N-hydroxyamides, N-hydroxyimines - with clusters or structured metal nanoparticles can generate free radicals of various structures that may enhance the catalysis or inhibition of oxidation. Aldimine and N-oxide complexes of metals is used as inhibitor models. Within the first phase of project the synthesis of complexes based on N-salicylaldimine were performed.The structures were fully characterized by IR spectroscopy and elemental analysis. Moreover a number of N- hydroxyimide with different substituents on the aromatic ring were synthetized for the study of their behaviour during the homogeneous aerobic oxidation. The purity of the compounds and their compliance with the target structure was confirmed by NMR spectroscopy and liquid chromatography. Also it carried out the synthesis of carbon nano-objects - nanoonions. Product Description popup.authors Камєнєва Тетяна Михайлівна Новікова Катерина Василівна Полункін Євген Васильович Терець Марія Іванівна Шелудько Євген Валентинович popup.nrat_date 2020-04-02 Close