Search academic texts

Information × Registration Number 0216U009172, 0116U007291 , R & D reports Title The catalytic effect of metal complexes and polynuclear clusters on the homogeneous oxidation of organic compounds popup.stage_title Head Kompanets Mikhail, Registration Date 28-12-2016 Organization LM.Litvinenko Institute of Physical Organic and Coal Chemistry popup.description2 The purpose of the project - creation of new systems for the positive and negative catalysis processes, which could initiate (or inhibit) the oxidation of organic compounds. In the second phase of the project we made a study of inhibitory properties within a series of newly synthesized aldymine complexes. It was shown that the best inhibitory properties was clearly demostrated by the non-chelate complex of tin tetrachloride and salicylal-p-toluidine. Investigation of the influence of 3-hydroxyimino-2,4 - dioxypentane on isopropyl benzene and benzyl alcohol aerobic oxidation has disclosed the use of this oxime as oxidation inhibitor. We have alsso investigate the catalytic activity of previously synthesized series of N-hydroxyphthalimides in aerobic oxidation of isopropylbenzene. It iwas shown that the nature of substituents effect both the rate and selectivity of this reaction Product Description popup.authors Камєнєва Тетяна Михайлівна Новікова Катерина Василівна Полункін Євген Васильович Терець Марія Іванівна Шелудько Євген Валентинович popup.nrat_date 2020-04-02 Close