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Information × Registration Number 0217U001096, 0115U004328 , R & D reports Title Construction of coordination compounds of d-metals based on chalcohalides and derivative of carbothioamides with valuable biological, physical and technical properties popup.stage_title Head Baranets Sviatoslav Olexandrovych, Registration Date 23-01-2017 Organization V.I.Vernadskii Institute of General and Inorganic Chemistry NASU popup.description2 Liquid chalcohalide medias Chal2Hal2 (Chal - S, Se; Hal - Cl, Br) have been used as a precursors of synthesis new chalcohalides of PGMs (Ru, Rh, Os, Ir). Structure of family of isostructure Se9-containing compounds, which hav composition Rh2Se9Hal6 have been investigated. Structure of Os2Se2S6Cl8 and Ru2Se6Br12 have been clarified. All these compounds are binuclear and crystalize in their own structure types. They have been investigated using vibrational spectroscopy (IR, Raman). The new coordinative compounds of Ag(І) and Pd(II) with derivative of carbothioamides [AgHL1NO3]n, ([AgHL1NO3]·3H2O)n, [PdHL1]Cl2·H2O. Molecular structure of their compouns have been found and spectral properties have been investigated. Product Description popup.authors Репіч Гліб Геннадійович popup.nrat_date 2020-04-02 Close