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Registration Number

0217U001883, 0117U003205 , R & D reports

Title

Synergistic organic catalytic systems «N-hydroxyimides – metallic nanoparticles» in the oxidation of organic substrates by molecular oxygen

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Head

Opeyda Yosyp Oleksijovych,

Registration Date

31-07-2017

Organization

LM.Litvinenko Institute of Physical Organic and Coal Chemistry

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The aim of research is to create a new selective synergistic catalytic systems "Organocatalyst - Metal nanoparticles" involving nanoparticles of copper, silver and nickel for oxidation processes of organic substrates via C-H bonds to important oxygen compounds - monomers and intermediates with the aim of obtaining of valuable polymers for different purposes; study of the effect of composition organocatalytic systems "N-hydroxyimide - metallic nanoparticles" at the processes of oxidation of organic substrates by molecular oxygen and theoretical analysis using computer models of the kinetics of the process. Object of study - nanoparticles of copper, silver and nickel as the (co)catalysts for oxidation of organic substrates by molecular oxygen. Subject of investigation - initiated oxidation kinetics of cumene by molecular oxygen in the presence of nanoparticles of copper, silver and nickel. Methods - kinetic, energy-dispersive x-ray spectroscopy, X-ray analysis, scanning electron microscopy techniques, computer modeling. As a result of the research, mono- and bimetal nano-particles based on nickel, silver and copper with sizes <100 nm were synthesized; investigated the oxidation of organic substrates by molecular oxygen in the presence of synthesized magnetoseparative mono- and bimetallic nanoparticles.

Product Description

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Гринда Юрій Миколайович
Киця Андрій Романович
Кущ Ольга Василівна
Мідяна Галина Григорівна
Побігун-Галайська Олена Ігорівна
Хавунко Оксана Юліанівна

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2020-04-02