Search academic texts

Information × Registration Number 0217U002120, 0116U005702 , R & D reports Title Electrophysical and thermodynamic properties of liquid, solid and hybrid electrolytes: Statistical-mechanical approach popup.stage_title Head Holovko Myroslav, Доктор фізико-математичних наук Registration Date 19-01-2017 Organization Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine popup.description2 We studied the vapour-liquid phase behavior of ionic liquid in a rigid nanoporous matrix, which represents a basic model of the hybrid electrolyte system. For this purpose, we developed an appropriate theoretical approach, which is capable to provide a correct description of an ionic interaction with taking into account association phenomena in such a kind of systems. Numerical calculations are performed and gas-liquid phase diagrams of ionic liquid in disordered porous matrices are obtained. The effect of the matrix on the critical parameters of the liquid is studied, as well as dependencies of the ionic association degree on the porosity of the matrix, the size of its particles and on the matrix structure are analyzed. Also the effect of size-asymmetry of ionic liquid confined in disordered matrices is considered. The obtained results are published in 2 scientific articles. Product Description popup.authors Гвоздь Марта Валентинівна Пацаган Оксана Вадимівна Пацаган Тарас Миколайович Шмотолоха Володимир Ігорович popup.nrat_date 2020-04-02 Close