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Information × Registration Number 0217U003965, 0117U003206 , R & D reports Title The catalytic effect of metal complexes and polynuclear clusters on the homogeneous oxidation of organic compounds popup.stage_title Head Kompanets Mikhail, Registration Date 31-10-2017 Organization LM.Litvinenko Institute of Physical Organic and Coal Chemistry popup.description2 At the second stage of the project, we investigated the inhibitory properties of 3- (hydroxyimino) pentane-2,4-dione and Co(III) complex in aerobic oxidation of benzylic alcohol. We studied the reaction of phthalimid-N-oxyl radicals generation in the reaction of N-hydroxyphthalimides oxidation. It was shown, that main reason of phthalimide-N-oxyl radicals disappearance is the spontaneous decay. The constants of radicals decay were measured and it was shown that valus of constants decreased in the following order: NHPI, NHTPPI, 4-MeO-NHPI,4,5-diCl-NHPI Product Description popup.authors Новікова Катерина Василівна Раєнко Олена Валентинівна popup.nrat_date 2020-04-02 Close