Updated: 2025-12-07
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0217U006887, 0117U003167 , R & D reports
Study of thermobaric and composition stability of the perovskite-type phases in the ternary La2O3-Lu2O3(Y2O3)-Ln2O3 systems (where Ln = Er2O3, Yb2O3) for anisotropic textured laser matrices
Andrievskaya E.R,
21-12-2017
Frantzevich Insitute for Materials Science Problems of the Ukranian National Academy of Sciences
The phase equilibriums in binary systems in the temperature range 1600-1100 ° C are investigated, where the intermediate phase is organized / disordered and in triple systems at 1500 ° C in the whole range of concentrations. Based on the obtained results, the elements of the diagrams of the state of the specified systems are constructed. It is established that in systems La2O3-Er2O3 (Yb2O3) three types of solid solutions are formed: on the basis of hexagonal modification of A-La2O3, cubic modification of C-Ln2O3, and the ordered phase LaLnO3 (R) crystallizing in a perovskite-type structure with rhomboid curvature. The corresponding isothermal sections of state diagrams of triple systems are constructed. It was established that in the La2O3-Y2O3-Er2O3 (Yb2O3) systems, solid solutions based on cubic (C), hexagonal (A) and monoclinic (B) crystalline modifications of the initial components and ordered phases LaYO3, LaErO3, LaYbO3 are formed.
Биков О.І.
Власко Н.І.
Корнієнко О.А.
Рагуля А.В.
Чудінович О.В.
2020-04-02
Updated: 2025-12-07
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