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Information × Registration Number 0218U001155, 0115U003539 , R & D reports Title Creating supramolecular assemblies based surfactants for catalysis and molecular recognition popup.stage_title Head Anatolii F. Popov, Доктор хімічних наук Registration Date 24-01-2018 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 The research subjects are zwitterionic functionalized surfactants, pH-sensitive mixed micellar systems, organized molecular systems based on 3-pyridineboronic acid and its derivatives. The aim of the work is to control the reactivity of nucleophiles and to create the basis for the development of pH-sensitive functionalized zwitterionic micellar systems, the synthesis of functionalized surfactants to create new organized molecular systems that can be used for the utilization of ecotoxicants and the modeling of the action of enzymes. Methods of investigation - UV, IR, NMR, mass spectroscopy, potentiometry, dynamic light scattering, tensiometry, spectrofluorimetry, X-ray diffraction analysis, transmission electron microscopy, elemental analysis, general methods of synthetic and preparative chemistry. A comprehensive study and analysis of the aggregation properties of zwitterionic functionalized surfactants and their mixed micellar systems with conventional cationic CTAB and nonionic surfactant Tween® 80 and their micellar effects in the cleavage of activated esters is presented. Methods for the preparation of amphiphilic boronic acids using microwave activation that meet the requirements of "green chemistry" are proposed, new functionalized surfactants based on them are obtained. A water-soluble vesicular sensor system has been developed to recognize biologically important polyols. Product Description popup.authors Бєлоусова І.О. Бураков М.І. Гуменна М.А. Капітанов І.В. Карпічев Є.А. Кучеренко В.О. Мітченко О.С. Сердюк Г.О. Шумейко О.Є. popup.nrat_date 2020-04-02 Close