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Registration Number

0218U003578, 0113U001392 , R & D reports

Title

Kinetics and Mechanism of Functionalization of Organic Substrates to Practically Important Products in New Energy-Resource Catalytic Processes

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Head

POKUTSA ALEKSANDER PETROVICH,

Registration Date

10-04-2018

Organization

Physical Chemistry of Combustible Minerals Department Institute of Physical Organic Chemistry and Coal Chemistry of National Academy of Sciences of Ukraine

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It has been established that the oxidation of C6H12 in the presence of VO (acac)2 (1) can be significantly accelerated by the addition of small amounts of oxalic acid (2). These studies suggested the need for a more detailed study of the mechanism of influence 2 on this process. It has been shown that the higher (in comparison with the acid-free process) yield of cyclohexanol and cyclohexanone is due to the relatively higher level of metal-peroxo-intermediates. The free-radical component of the process was also thoroughly studied because products of purely free radical oxidation (cyclohexylhydroperoxide) were recorded both in the absence and in the presence of oxalic acid.

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Антонишин Ірина Степанівна
Балашова Ірина Єгорівна
Васютин Ярослава Михайлівна
Заборовський Андрій Богданович
Кубай Юлія Юріївна
Мідяна Галина Григорівна
Макітра Роман Григорович
Макогон Оксана Іванівна
Максим Дарія Степанівна
Ткач Сергій Олександрович
Федорчук Анатолій Олександрович
Флюнт Роман Ігорович

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2020-04-02