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Information × Registration Number 0218U003578, 0113U001392 , R & D reports Title Kinetics and Mechanism of Functionalization of Organic Substrates to Practically Important Products in New Energy-Resource Catalytic Processes popup.stage_title Head POKUTSA ALEKSANDER PETROVICH, Registration Date 10-04-2018 Organization Physical Chemistry of Combustible Minerals Department Institute of Physical Organic Chemistry and Coal Chemistry of National Academy of Sciences of Ukraine popup.description2 It has been established that the oxidation of C6H12 in the presence of VO (acac)2 (1) can be significantly accelerated by the addition of small amounts of oxalic acid (2). These studies suggested the need for a more detailed study of the mechanism of influence 2 on this process. It has been shown that the higher (in comparison with the acid-free process) yield of cyclohexanol and cyclohexanone is due to the relatively higher level of metal-peroxo-intermediates. The free-radical component of the process was also thoroughly studied because products of purely free radical oxidation (cyclohexylhydroperoxide) were recorded both in the absence and in the presence of oxalic acid. Product Description popup.authors Антонишин Ірина Степанівна Балашова Ірина Єгорівна Васютин Ярослава Михайлівна Заборовський Андрій Богданович Кубай Юлія Юріївна Мідяна Галина Григорівна Макітра Роман Григорович Макогон Оксана Іванівна Максим Дарія Степанівна Ткач Сергій Олександрович Федорчук Анатолій Олександрович Флюнт Роман Ігорович popup.nrat_date 2020-04-02 Close