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Information × Registration Number 0219U101770, 0115U004530 , R & D reports Title Construction of active sites on the surface of carbon and oxide nanomaterials and studying their reactivity in sorption, catalytic and electric-chemical processes. popup.stage_title Head Kartel Mykola T., Доктор хімічних наук Registration Date 31-10-2019 Organization Chuiko Institute of Surface Chemistry of NAS of Ukraine popup.description2  The catalytic ability of KAU and SKN coal, carbon nanotubes and their modified forms (oxidized, nitrogen-containing) and catalase enzyme in the model reaction of decomposition of benzoyl peroxide by calculating the constants of Michaeletis sublimation was experimentally determined. Carbon nanomaterials have been shown to exhibit a catalase ability in a non-aqueous environment. It is established that the catalytic ability of the studied samples correlates not with structural parameters but with changes in surface chemistry. The introduction of oxygen into the structure reduces, and the introduction of nitrogens increases their catalytic activity. The influence of the chemical state of the nitrogen atoms in the structure of CNM on its catalytic activity has been determined. It is shown that the catalytic enzyme activity of carbon nanomaterials correlates with the presence of Quaternary nitrogen in the composition. The synthesized nitrogen-containing carbon nanomaterials (N-CNMs) exceed the activity of native catalase in a non-aqueous environment, making them promising catalysts for the decomposition of organic peroxides. Product Description popup.authors Belyakova Lyudmila O. Bakalinska Olga M. Brichka Alla V. Vlasova Nataliia M. Voitko Kateryna V. Dzyasko Maryna O. Kuksenko Serhii P. Lyaschenko Diana Yu. Nikolaichuk Alina A. Nasedkin Dmytro B. Roik Nadiya V. Sementsov Yurii I. Tarasenko Yuriy O. Trofymchuk Iryna M. popup.nrat_date 2020-04-02 Close