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Information × Registration Number 0221U000142, 0117U000097 , R & D reports Title Bioresources - alternative raw materials for the chemical industry. popup.stage_title Head Kashkovskiy Volodymyr I., Кандидат хімічних наук Registration Date 02-01-2021 Organization V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine popup.description2 Butanol transesterification of products of the acid homogeneous-catalytic stage (esterified rapeseed and mustard oil with reduced to 0.37 and 1.23% FFA content) on potassium butylate was carried out. In the case of both oils, the ester layers contained only 0.5-0.6% glycerol and had a black-brown colour. Sulfur-containing surfactants have been synthesized on the basis of technical fats and products of their chemical transformation and the conditions for their production have been optimized. Hydrolysis of glucose and fructose, as components of bio raw materials, on heterogeneous catalysts has shown the possibility of obtaining various chemicals, and the range of these compounds is quite wide. Calculations were made to obtain the initial parameters for the design of a pilot plant for the production of pectin concentrate. From the obtained products of thermoconversion of biomass, a hydrocarbon fraction was isolated, the composition of which was determined by gas chromatographic method, which was further processed on an aluminium-silicon catalyst at a temperature of 350 oC and atmospheric pressure. Obtained a component of motor fuel with an octane number of not less than 80. Synthesized hydrophobic ionic liquids, which include cations of 1-octyl-3-methylimidazole, 1,3-dioctylylimidazolium, 1-octylpyridinium, 1-octyloxycarbonylmethylmethyl-3-methyl. Acid residues of butylricinoleate sulfated and acylated with succinic anhydride and lauric acid were used as anions. Bifunctional catalysts for hydrogenation of CO2 in DME and methanol-based on copper-zinc-alumina catalyst CHM-У as a hydrating component and zeolite HMFI modified with oxides of aluminium and zirconium as a dehydrating agent were obtained. The course of the hydrogenation reaction of CO2 in DME and methanol on the obtained bifunctional catalysts on a catalytic chromatographic unit depending on the temperature in the range of 200–260 °С under a pressure of 1.0 MPa was studied. Product Description popup.authors Yevdokymenko Vitaly O. Aksenovska Olesya A. Aksylenko Maryna D. Bereznitskiy Yaroslav O. Bogomolov Yuriy I. Bodachivska Larisa Yu. Venger Irina О. Verba Artem Yu. Voloshyna Yuliya G. Gayday Olga О. Davitadze David Z. Dzhuzha Oleg V. Dolia Lidia P. Zlochevskyi Kostiantyn V. Zubenko Stepan О. Kameneva Tatiana M. Kamenskyh Dmytro S. Kobyzhcha Nataliya I. Konovalov Serhiy V. Melnykova Svіtlana L. Melnychuk Oleksandr V. Pavliuk Oleksandr V. Papeikin Oleksii O. Patryliak Liubov K. Pertko Oleksandra P. Pyliavsky Volodymyr S. Povazhnyi Volodymyr А. Polunkin Yeugene V. Reshetar Tamara P. Rogalsky Sergiy P. Safronov Oleg І. Starzhynska Ludmila І. Sukhoveev Volodymyr V. Tarasyuk Oksana Р. Tkachenko Tetiana V. Khimach Natalia Yu. Sheludko Yevgeniy V. Shybyryn Olena V. Yakovenko Angela V. popup.nrat_date 2021-01-02 Close